Polyvinylidene fluoride (PVDF) is an electroactive polymer, which has highly gotten attention by the researchers due to piezoelectric, pyroelectric, chemical stability and ferroelectric properties. But the only disadvantage of this polymer is that its electro-active properties are weaker than the ceramic counterparts. In order to eliminate this problem, it was suggested that this polymer get composed with an electro-active ceramic. The composition of electro-active ceramics and ferroelectric polymers is very important for applications, because they combine the most important features of both phases, and their properties can easily be adapted to different situations. In this study, ZnO nanoparticles were synthesized by thermal decomposition of acetates in the presence of citric acidic. The polycrystalline sample of 0.94PFN-0.06PT was also synthesized by solid-state reaction. Then the PVDF polymer was composed with ZnO nanoparticles and electro-active ceramic PFN-PT separately; so their electrical and ferroelectric properties were significantly improved. In addition, only by manipulating the solvent and PVDF polymer processing conditions, the ferroelectric phase (?) of this polymer was increased from 49% to 78%, and by adding ZnO nanoparticles up to 94%, which is a remarkable achievement. To investigate the structural, electrical and dielectric properties of materials, X-ray diffraction analysis, polarization vs electric field hysteresis and electrical permittivity vs temperature were performed. Besides, FTIR analysis also used to calculate the ?-phase percent of the samples. It should be noted that for conducting the polarization vs electric field analysis, the Sawyer-Tower arrangement was improved in this project. Finally, the samples 0.85PVDF/0.15ZnO and 0.8PVDF/0.2PFN-PT were introduced as the best samples in terms of high ?-phase and relatively great ferroelectric and dielectric properties.