Electrospraying is a promising tool for producing high-quality films and thin films. Electrospraying use electric forces for liquid deposition. The advantage of electrospraying is that the droplets can be very small, and the charge and size of droplets can be controlled to some extent by adjusting the flow rate of the fluid and the voltage applied to the nozzle. The purpose of this research is to produce thermoelectric textiles used in clothing. . First, the critical conditions for the production of nanofiber / nano-microparticles were evaluated by the electro centrifuge spinning system. In this section, the critical voltage and Rotational speed were obtained, which is the limit of access to microparticles or nanofibres. In the meantime, this study was conducted to investigate the jet's behavior in electro centrifuge process. Subsequently, suitable conditions for the uniform coating of polyvinyl-pyrrolidone (PVP) microparticles were evaluated. In this study, materials such as CNT, PPV, PPY Cuo were used to obtain suitable thermoelectric properties. Cotton fabrics were covered with Polymerization in the PolyPyrrole. The solution containing the pvp, cuo, and cnt was then electrosprayed on the synthesized fabric. .SEM, FTIR, electrical conductivity, Seebeck coefficient, thermoelectric tests were performed. It should be noted that all experiments were performed on the basis of the Taguchi test design. Accordingly, the highest electrically conductivity of the polypyrrole-coated fabric with dupant containing 20% carbon nanotube and 20% copper oxide nanoparticles is equal to 1.2973s/cm and the highest coefficient of seebeck and electrical power obtained for this sample of the fabric is equal to5.5789µv/k^(-1),40.3773µwmk^2.