Comfort is defined as a desirable state of mental and physical harmony between human and environment. A high level of energy is produced by human body during heavy activities and exercises, which results in higher body temperature. Body produces a lot of sweat to reduce its temperature. The produced sweat has to be transferred to the environment to achieve comfort. This study was aimed at enhancing the moisture transfer capability of a hydrophobic spun-bond polypropylene (PP) non-woven on which hydrophilic polymers such as poly acrylonitrile (PAN) with silicon oxide Nanoparticles (SiO2 )or nylon 6 (N6) are electrospun. This was implemented by modifying surface properties of the non-woven using graft polymerization of acrylamide. According to the results, the diameter of fibers in the non-woven layer was increased at higher concentrations of acrylamide monomer in the solution. The graft polymerization was confirmed by qualitative and quantitative evaluation of functional groups as well as decreasing the water contact angle on the surface of nonwoven. It was also observed that air permeability of the nonwoven was not affected by the surface modification process. Based on the results associated with evaluation of moisture management and the values of OMMC (overall moisture management capacity) = 0.75 and OWTC (one-way moisture transfer capability) = 494.06, it can be said that the dual-layer structure composed of the non-woven modified by 20% (w/v) acrylamide solution and PAN+SiO2 electrospun layer exhibits superior performance over the other dual-layer structures. Given the water vapor transfer rate, the mentioned sample can be regarded to be breathable.