In this work, improved the electrocatalytic properties of Copper nanofoam by electrochemical deposition of Nickel and Cobalt particles. At First, Copper nanofoam was formed by cyclic voltammetry method in 0.5M H2SO4 Solution on Copper plate by needle structure. Then, the deposition of Nickel and Cobalt particles has been carried out using two method step potential and cyclic voltammetry. The structure of prepared electrocatalyst has evaluated by SEM, EDS, XRD techniques. Effect of applied potential, time, number of cycles, scan rate, the ratio of Ni and Co and total concentration of deposition solution was evaluated. Electrocatalytic activity of the catalyst was also investigated by linear sweep voltammetry in the 0.5M H2SO4 solution. The results show that Ni-Co@Cu Foam catalyst with Tafel slope of 38.3 mV dec-1, current density of -10 mA.cm-2 in overpotential of -8 mV vs. RHE has good stability in acidic media, is an extremely suitable catalyst in hydrogen evolution reaction.