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SUPERVISOR
امید معینی جزنی (استاد راهنما) محمود معصومی (استاد راهنما)
 
STUDENT
Shadi Rownaghzade
شادی رونق زاده

FACULTY - DEPARTMENT

دانشکده مهندسی شیمی
DEGREE
Master of Science (MSc)
YEAR
1395

TITLE

Investigating the effect of SEBS-g-MA compatibilizer percentage and blend components on morphology and its relationship to mechanical properties of PP/PBT/SBS ternary polymer blends
Increasing the toughness of polypropylene with an elastomer has been suggested by researchers in the field of polymer science and technology. Now due to the decrease of mechanical properties by adding elastomer, adding a third stiff component seems to be necessary to prevent the decrease of mechanical properties. Therefore, in this project, the factors affecting the morphology of the polypropylene/poly(butylene-terephthalate)/ styrene-butadiene-styrene ternary system and their relationship with the mechanical properties have been studied. In this regard, the effect of the two factors including the composition of compatibilizer (styrene-ethylene-butylene-styrene grafted on maleic anhydride) and the composition of PBT and as the effective factors on the morphology was investigated. It was found that by changing the ratio of to SEBS-g-MA in the constant composition of the blend components (PP/PBT/:70/15/15), the morphology and mechanical properties (modulus, tensile strength, yield stress, elongation at breakpoint) and the impact strength were affected by the presence of this evolution, which reduced Young apos;s modulus from 1263 to 908 (MPa) and increased the impact strength from 3.82 to 10.6 (kJ/m2). Also by increasing the rubber phase from 5 to 30 wt% of the System, the Young apos;s Modulus decreased from 1290 to 823.8 MPa and its impact strength increased due to the presence of core-shell microstructures and independent rubber droplets from 4.49 to 47.9 (kJ/m2). It was also found that by increasing the composition of the PBT composition from 5 to 30 wt%, the rod-like microstructure gradually formed and Young apos;s modulus gradually increased from 1167.5 to 1430 MPa, but still decreased with respect to the matrix phase. This is due to the complex morphology observed and the impact strength decreased from 5.9 to 4.09. Finally, the optimum sample was reported to be 72% wt% PP, 20% wt% PBT, 8% wt% of the total and SEBS-g-MAH with 50.50% lower than pure PP. Keywords : Mechanical properties, Polypropylene (PP), styrene-ethylene-butylene-srtyrene (), Polybutyleneterephthalate (PBT), Ternary polymer blends, Core-shell morphology
سازگارکننده قرار می گیرد که مدول یانگ از ???? به 908 (مگاپاسکال) کاهش و استحکام ضربه از 82/3 به 6/10 (کیلوژول بر مترمربع) افزایش یافت. همچنین با افزایش فاز رابری از 5 تا 30 درصد وزنی مدول یانگ سامانه از 1290 به 8/823 مگاپاسکال کاهش و استحکام ضربه آن بدلیل حضور ساختارهای هسته- پوسته و قطرات مستقل رابری از 49/4 به 9/47 (کیلوژول بر مترمربع) افزایش می یابد و همچنین با افزایش ترکیب درصد فاز سخت PBT از 5 تا 30 درصد وزنی بتدریج ریز ساختار میله ای تشکیل شده و مدول به تدریج از 5/1167 به 1430 مگاپاسکال افزایش یافت اما همچنان نسبت به فاز ماتریس کاهش نشان می دهد که این امر بدلیل ریز ساختار پیچیده مشاهده شده می باشد و استجکام ضربه از 9/5 به 09/4 کاهش یافت. در نهایت نمونه بهینه با توجه به کمترین افت خواص نسبت به پلی پروپیلن خالص گزارش گردید که شامل72 درصد وزنی PP ، 20 درصد وزنی PBT ، 8 درصد وزنی از مجموع و SEBS-g-MAH به نسبت 50/50 می باشد. کلمات کلیدی: خواص مکانیکی ، پلی پروپیلن ،استایرن بوتادین استایرن تری بلاک کوپلیمر ( ) ، پلی بوتیلن ترفتالات ( PBT ) ، آلیاژ سه تایی ، ریزساختار هسته – پوسته

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