Replace fossil fuels with renewable sources, has attracted much attention. Types of low temperature fuel cells, are a good option to replace fossil fuels. Hydrogen fuel cells are one of the alternatives. Direct alcohol fuel cells (DAFCs) have attracted enormous attention as power sources for portable electronic devices and traortation because liquid alcohol fuels have a higher energy density and are easier to handle and store than hydrogen gas fuel. Among various types of alcohols, 1-propanol is one of the most promising candidates for direct alcohol fuel cells (DAFCs). 1-Propanol is less toxic than methanol, it is less prone to crossover to the cathode, and it is not poison to the cathode like the methanol. 1-propanol is linear alcohol has an inherently a high energy density, due to the liquid, easily stored and also chemically stable, non-flammable, so a good option for fuel cell research n-propanol directly between fuel cells. In the present study, we introduce on the first time Pt-free Hypermec TM as anode electrocatalyst, which is high electrocatalytic activity then other Pt-free electrocatalyst for electrooxidation of 1-propanol in alkaline media. Performance of this electrode compared to Pd/C (10 wt. %) this ability have been done by cyclic voltammetry (CV) and chronoamperometry. Finally, Pt-free Hypermec TM catalyst were incorporated into the passive air breathing direct 1-propanol fuel cell. The electrocatalytic oxidation of n-propanol was studied on Pt-free Hypermec TM (Fe-Co-Ni) nanocatalysts and Pd supported over commercial carbon electrodes in 0.1 M KOH solution at room temperature. Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and chronoamperometry techniques were employed. Scanning electron microscopy (SEM) was also employed to morphological study of the catalyst layer. In this project, a porous anode electrode based on Pt-free Hypermec TM nanocatalyst was prepared for the evaluation of 1-propanol electrooxidation in alkaline media. The morphological characterization and treatment of nano catalysts studied by scanning electron microscope (SEM). The images showed porous structures for catalysts that create desirable distribution for fule on the catalyst surface. Performances of the Pt-free electrode and conventional palladium anode electrode in 1-propanol electro oxidation reaction were compared. The Pt-free Hypermec TM showed a higher activity toward n-propanol oxidation than the d/C (10 wt. %), in the cyclic voltammetry measurement. The chronoamperometry results showed clearly that the Hypermec TM is a better catalyst for n-propanol oxidation reaction than the Pd/C (10 wt. %). The ratio of the current response of the forward anodic peak (I f ) to their verse anodic peak (I b ) is a measure of the fraction of the catalyst surface which has not been poisoned.The higher value of I f /I b , is equivalent to less poisoning of the electrode. Within the error limits, the value of I f /I b obtained for the Pt-free Hypermec TM (0.68) was comparable to the 0.75 for Pd/C (10 wt. %). The maximum current density value obtained for the Pt-free Hypermec TM was 63 µA.µg -1 metal and for Pd/C (10 wt. %) was 48 µA.µg -1 metal in present the fuel. Therefore, the Hypermec TM electrocatalyst had a higher catalytic activity than Pd/C (10 wt. %) electrocatalyst. Moreover, n-propanol oxidation reaction on the tow electrode is diffusion-controlled and represents a good linear correlation with propanol concentration. The results indicate that Pt-free Hypermec TM (Fe-Co-Ni) nanocatalysts is attractive as a promising electrocatalyst of alkaline direct 1-propanol fuel cells.