In this research, the production of a sulfone-graphene oxide catalyst for the sterification of glycerol, as well as ethylene glycol with acetic acid and the production of value added compounds, including glycerol acetates and ethylene glycol acetates, was studied. In the first part of this study, a sulfone-based graphene oxide catalyst was developed. In order to study the properties of the catalyst and also the changes made during the construction of the catalyst, solid samples were studied in different stages by FT-IR, XRD, FE-SEM, TGA, BET and Raman methods. The acidity of the catalyst was also determined by inverting titration. Its activity was investigated in the reaction of acetylation of glycerol with acetic acid in a batch system using toluene azoteotropic agent. The reaction of styrilization of glycerol with acetic acid at the formation of the a-toluene azototropic temperature (100-94 ° C), the molar ratio of 7 to 1 acetic acid to glycerol and 7% by weight of the catalyst (relative to glycerol weight) and the effect of the catalyst Based on the percentage of glycerol conversion and triacetine selectivity was investigated. After 3 hours of reaction, the conversion rate of 98.4 for glycerol and selectivity was 12.3, 45.1 and 44.6 for monoacetine, diacetine and triacetine, respectively. In the following, the performance of the catalyst made with other catalysts, such as amberlyst 36, levatite, peurolite, citric acid, malic acid, paratolone sulfonic acid, and graphene oxide were compared. The stability of the catalyst was also evaluated through 4 repetitive trials at 3-hour intervals. In the next section of this paper, the catalytic activity of sulfonated graphene oxide was evaluated in the reaction of ethylene glycol with the acetic acid esterification in a batch system using toluene azeotropic agent. In optimal conditions, 5% by weight of the catalyst, the molar ratio of 4 to 1 acetic acid to ethylene glycol and 2 hours of reaction, the conversion percentage of 100 for ethylene glycol for selectivity was 24.4 and 75.6 for ethylene glycol monoacetate, and Ethylene glycol diacetate were obtained. In the following, the performance of the catalyst made with other catalysts, such as amberlyst 36, levatite, peurolite, citric acid, malic acid, paratolone sulfonic acid, and graphene oxide were compared. The catalyst stability was also investigated by repeated experiment at 2 hours.