Amorphous alloys are some of the most significant advanced materials, which have been left unnoticed in the last decades in comparison with crystalline solids. In contrast to crystalline solids that contain long-range-order and lattice defects, amorphous alloys have a disorganized and short-range-ordering in atomic structure. Therefore, amorphous solids have exceptionally different physical, chemical and mechanical characteristics such as higher strength, hardness, toughness, and elasticity and better overall corrosion resistance. It is undeniable that amorphous alloys have good wear resistant, meaning that by incorporating amorphous coating on metal materials, we could protect metals from extreme damages of severe wear and erosion. The properties mentioned above are the reason that amorphous materials are used in various industries such as aerospace, automotive and magnetic engineering Mechanical alloying (MA) is the most important method of solid-state amorphisation. In MA there is no need for a high temperature, making amorphisation easier and more cost effective. Another advantage of MA in comparison with other methods is that they have a greater amorphous phase formation range [3–5] . Overall, the mechanical alloying process can cause a progressive increase in lattice defects in the structure and also a decrease in the grain size. Therefore, the amorphisation reaction will be thermodynamically and kinetically affected. In fact, in order to allow a high diffusion rate at low temperature and therefore permit the amorphisation reaction to take place kinetically, it is necessary to have several high-speed diffusion paths such as sub-grain boundaries and dislocation networks
